Enhanced Anion‐derived Inorganic‐dominated Solid Electrolyte Interphases for High‐rate and Stable Sodium Storage
نویسندگان
چکیده
It is highly desirable for the promising sodium storage possessing high rate and long stable capability, which are mainly hindered by unstable yet conventional solvent-derived organic-rich solid electrolyte interphases (SEI). Herein, an solvation chemistry elaborately manipulated to produce enhanced anion-derived inorganic components-dominated SEI introducing a low permittivity (4.33) bis(2,2,2-trifluoroethyl) ether (BTFE) diluent into bis(fluorosulfonyl)imide (NaFSI)-dimethoxyethane (DME)-based concentration (HCE) obtain localized HCE (LHCE). The BTFE breaks balance of original cation structure tends interact with Na+-coordinated DME solvent rather than Na+ in HCE, leaving Coulombic interaction between FSI−, more FSI− can enter shell, forming further increased number Na+-FSI−-DME clusters (from 82.0% 94.3% LHCE) at salt dosage. preferential reduction this FSI−-enriched DME-dominated produces SEI. reversible charge process Na decoupled operando Raman along shift D G peaks. Benefiting from electrode-electrolyte interface, commercial hard carbon anode LHCE shows well capability (5 A g−1, 70 mAh g−1), cycle performance stability (85% initial capacity after 700 cycles) comparison that (68%) (only 5% 400 cycles), indicative uniqueness superiorities towards storage.
منابع مشابه
Solid Electrolyte Interphases: A Review of Solid Electrolyte Interphases on Lithium Metal Anode (Adv. Sci. 3/2016)
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ژورنال
عنوان ژورنال: Energy & environmental materials
سال: 2023
ISSN: ['2575-0348', '2575-0356']
DOI: https://doi.org/10.1002/eem2.12602